Chemical Entity

Free Chlorine

The active, unsaturated chlorine available to sanitize pool water.

Definition

Free chlorine (FC) is the portion of chlorine in pool water that has not yet reacted with contaminants. It exists primarily as hypochlorous acid (HOCl) and hypochlorite ion (OCl−). HOCl is the active sanitizing form and is 40–80× more effective than OCl−. The ratio of HOCl to OCl− is determined by pH — lower pH means more HOCl. Free chlorine must be maintained above the minimum level dictated by the cyanuric acid concentration.

Quick Facts

Ideal Range
1–3 ppm
Units
ppm
Also Known As
FC, free chlorine, available chlorine, FAC, residual chlorine, pool chlorine

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